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User Comments: 

#1
Thank you for your massive effort in doing and maintaining this XPS database with precise and qualitative data! I appreciate your help as an XPS user!
I want to be a Library Member. Thank you!
Alexandru M. in Mexico

#2
Good for you; as a modest practitioner of XPS myself, I really appreciate all the educational materials you have have made available over the years.
Wishing you good luck,
David B. in Norway

#3

     

The XPS Library
bvcrist@xpslibrary.com
Founded:  June, 2018
©B. Vincent Crist, 2018-2024, All rights reserved

 



 

“You know, it would be sufficient to really understand the electron.”   A.E.

 



 

Link to

The International XPS Database of XPS Reference Spectra

Raw spectra, Peak-fits and Six (6) BE Tables



Examples of XPS Reference Spectra in The International XPS Spectra-Base

Beryllium (Be), Z=4

Beryllium (Be), Z=4.


Beryllonite – BePO4

Beryl – Be3Al2Si6O18


Beryllium (Be), Z=4



Peak-fit of Be (1s) XPS Spectrum from
ion etched Beryllium metal, Beo
Peak-fit of C (1s) XPS Spectrum from
ion etched Beryllium metal, Beo


Overlay of Be (1s) XPS Spectra from
Beryllium metal, Beo , and BeO powder
Peak-fit of Be (1s) XPS Spectrum from Native Be Oxide, BeOx
on Beryllium metal, Beo


Overlay of Beryllium Valence Band XPS Spectra from
Beryllium metal, Beo , and Beryllium Sulfate, BeSO4
Overlay of Be (1s) XPS Spectra from Beryllium metal, Beo,
Beryllium Oxide. BeO, and Beryllium Fluoride, BeF2


O (1s) XPS Spectrum from
Beryllium Sulfate, BeSO4
Peak-fit of S (2p) XPS Spectrum from
Beryllium Sulfate, BeSO4


Chromium (Cr), Z=24 .Chromium (Cr), Z=24

Eskolaite – Cr2O3

Uvarovite  – Ca3Cr2(SiO4)3


Chromium (Cr), Z=24



Cr (2p) XPS Spectrum from
Chromium Oxide, Cr2O
(single crystal)
Cr (2p3/2) XPS Spectrum from
Chromium Oxide, Cr2O
(single crystal)


Peak-fit of Cr (2p) XPS Spectrum from
Chromium Oxide, Cr2O
(single crystal)
Overlay of Cr (2p) XPS Spectra from
Chromium Oxide, Cr2O3, Chromium metal, Cro and Native Cr Oxide


Peak-fit of Cr (3s) XPS Spectrum from
Chromium Oxide, Cr2O
(single crystal)
Example of Multiplet Splitting in (3s) orbitals
Overlay of Chromium Valence Band XPS Spectra from
Chromium Oxide, Cr2O3, and Chromium metal, Cro

.

Cuprite – Cu2O

Tenorite – CuO


Copper (Cu), Z=29



Overlay of Cu (2p3/2) XPS Spectra from
anhydrous Copper Sulfate, CuSO4, and ion etched Copper metal, Cuo 
Overlay of Copper Valence Band XPS Spectra from
anhydrous Copper Sulfate, CuSO4, and ion etched Copper metal, Cuo 


Cu (2p) XPS Spectrum from
anhydrous Copper Sulfate, CuSO4
Peak-fit of Cu (2p3/2) XPS Spectrum from
anhydrous Copper Sulfate, CuSO4
Example of Multiplet Splitting


Peak-fit of C (1s) XPS Spectrum from
anhydrous Copper Sulfate, CuSO4
Peak-fit of S (2p) XPS Spectrum from
anhydrous Copper Sulfate, CuSO4


Peak-fit of Cu (3s) XPS Spectrum from
anhydrous Copper Sulfate, CuSO4
Example of Multiplet Splitting
Peak-fit of Cu (3p) XPS Spectrum from
anhydrous Copper Sulfate, CuSO4
Example of Multiplet Splitting


.

Martite  –  α-Fe2O3

Siderite – FeCO3


Iron (Fe), Z=26



→Periodic Table →Support Information
Fe (2p) XPS Spectrum from
Iron Oxide, α-Fe2O3 (Hematite, 
natural crystal)
Fe (2p) XPS Spectrum from
Iron Mono-Oxide, FeO


→Periodic Table →Support Information
Fe (2p3/2) XPS Spectrum from
Iron Oxide, α-Fe2O3 (Hematite, 
natural crystal)
Overlay of Fe (2p3/2) XPS Spectra from Iron metal (Feo),
Iron Mono-oxide (FeO), Hematite, (α-Fe2O3) and Magnetite (Fe3O4)


→Periodic Table →Support Information
Overlay of Fe (2p) XPS Spectra from Iron metal (Feo), Iron Mono-oxide (FeO),
Hematite, (Fe2O3
natural crystal) and Magnetite (Fe3Onatural crystal)

Overlay of Fe (2p) XPS Spectra from Iron metal (Feo), Iron Mono-oxide (FeO),
Hematite, (Fe2O3
natural crystal) and Magnetite (Fe3Onatural crystal)



→Periodic Table →Support Information
Peak-fit of O (1s) XPS Spectrum from
Iron Oxy-hydroxide (α-FeO(OH), 
natural crystal)
Overlay of Fe (2p3/2) XPS Spectra from
Iron metal (Feo), Iron Oxy-hydroxide (α-FeO(OH)), and Hematite, (α-Fe2O3)


Overlay of Iron Valence Band XPS Spectra from
Iron metal (Feo), and Iron Oxy-hydroxide (FeO(OH), 
natural crystal)
Overlay of Fe (2p3/2) XPS Spectra from Iron metal (Feo),
Iron Oxy-hydroxide (FeO(OH)), and Hematite, (α-Fe2O3
natural crystal)


.

Magnesite – MgCO3

Sellaite – MgF2


Magnesium (Mg), Z=12


→Periodic Table →Support Information
Ultra-High Energy Resolution Mg (2p) XPS Spectrum from
Magnesium metal, Mgo
Mg (1s) XPS Spectrum from
Magnesium metal, Mgo


→Periodic Table →Support Information
Peak-fit of C (1s) XPS Spectrum from
Magnesium Hydroxide, Mg(OH)2
Peak-fit of Mg (2p) XPS Spectrum from
Magnesium Hydroxide, Mg(OH)2


→Periodic Table →Support Information
Peak-fit of Mg (2p) XPS Spectrum from
Magnesium Oxide, MgO
 (single crystal)
Peak-fit of Mg (2p) XPS Spectrum from
Magnesium Fluoride, MgF(crystallites)


→Periodic Table →Support Information
Overlay of Mg (2p) XPS Spectra from Magnesium metal, Mgo, and
Magnesium Hydroxide, Mg(OH)2, (Brucite, 
natural crystal)
Overlay of Mg (2p) XPS Spectra from Magnesium metal, Mgo,
Magnesium Oxide (MgO, 
single crystal) and Magnesium Fluoride (MgF2)


→Periodic Table →Support Information
Mg (2p) and Mg (2s) XPS Spectrum from
Magnesium Oxide (MgO, 
single crystal)
F (1s) XPS Spectrum from
Magnesium Fluoride (MgF2crystallites)


→Periodic Table →Support Information
XPS Survey Spectrum from Magnesium Hydroxide, Mg(OH)2  (Brucite, natural crystal)
(A test of Scofield Cross-sections, IMFP correction, and TF correction)

XPS Survey Spectrum from Magnesium Fluoride, MgF2 (crystallites)
(A test of Scofield Cross-sections, IMFP correction, and TF correction)
→Periodic Table →Support Information


.

Rutile – TiO2

Anatase – TiO2


Titanium (Ti), Z=22


→Periodic Table →Support Information
Ti (2p) XPS Spectrum from
ion etched Titanium metal, Tio
Peak-fit of Ti (2p) XPS Spectrum from
ion etched Titanium metal, Tio


→Periodic Table →Support Information
Ti (2p) XPS Spectrum from
strongly ion etched Titanium Nitride, TiN
Overlay of Ti (2p) XPS Spectra from
Titanium metal, Tio, and Titanium Nitride, TiN


→Periodic Table →Support Information
Peak-fit of Ti (2p) XPS Spectrum from
Titanium Dioxide, TiO2, (
single crystal, Rutile type)
Overlay of Ti (2p) XPS Spectra from
Titanium metal, Tio, Native Ti Oxide, and Titanium Dioxide, TiO2


→Periodic Table →Support Information
Peak-fit of C (1s) XPS Spectrum from
ion etched Titanium Nitride, TiN
Peak-fit of Ar (2p) XPS Spectrum from
Ar+ ion etched Titanium metal, Tio


.

Zincite – ZnO

Sphalerite – ZnS


Zinc (Zn), Z=30


→Periodic Table →Support Information
Peak-fit of Zn (2p3/2) XPS Spectrum from
ion etched Zinc metal, Zno
Peak-fit of Zn (2p3/2) XPS Spectrum from Zinc native Oxide, ZnOx
The peak at 1022.9 eV is probably due to Zn(OH)not ZnO.


→Periodic Table →Support Information
Overlay of Zn (2p3/2) XPS Spectra from
ion etched Zinc metal, Zno, and Zinc native Oxide, ZnOx
Overlay of Zn (2p3/2) XPS Spectra from
ion etched Zinc metal, Zno, and Zinc Oxide, ZnO, 
(single crystal)


→Periodic Table →Support Information
Overlay of Zn (2p3/2) XPS Spectra from
ion etched Zinc metal, Zno, and Zinc Selenide, ZnSe, 
(single crystal)
Overlay of Zn (2p3/2) XPS Spectra from
Zinc metal, Zno, Zinc Oxide, ZnO, Zinc Sulfide, ZnS, and Zinc Selenide, ZnSe 


→Periodic Table →Support Information
Overlay of Loss Peaks in Zn (2p) XPS Spectra from
ion etched Zinc metal, Zno, and Zinc Selenide, ZnSe, 
(single crystal)
Overlay of Zn (KLL) XPS Spectra from ion etched
Zinc metal, Zno, and Zinc Sulfide, ZnS, and Zinc Oxide, ZnO 
(single crystal)






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